Concepedia

Diethyl Thioxomalonate<i>S</i>‐Oxide; a Sulfine as Reactive Intermediate

Rolf W. Saalfrank, Walter Rost

Angewandte Chemie International Edition in English · 1985 · 25 citations · 9 references

DOI

Concepts

Abstract

The heteroallene 1, formed as an intermediate in the reaction of tetraethoxyallene with thionyl chloride, can be trapped by dimethylbutadien0e in a Diels-Alder reaction before it dimerizes to a 1,2-dithietane.

References

9

A titanium vinylidene route to substituted allenes

Stephen L. Buchwald, Robert H. Grubbs · Journal of the American Chemical Society · 1983 · 104 citations

, , +5

Synthesen von Moniliformin, einem Mycotoxin mit Cyclobutendion‐Struktur

D. BELLUS, Hans‐Peter Fischer, Hans Greuter et al. · Helvetica Chimica Acta · 1978 · 67 citations

, , +7

The chemistry of sulfines. 6. Dimer of the onion lachrymatory factor: the first stable 1,2-dithietane derivative

Eric Block, Ali A. Bazzi, Larry K. Revelle · Journal of the American Chemical Society · 1980 · 53 citations

, , +5

Dithiiranes and Thiosulfines as Reactive Intermediates

Alexander Senning · Angewandte Chemie International Edition in English · 1979 · 35 citations

, , +2

Preparation of sulfines by alkylidenation of sulfur dioxide using α‐silyl carbanions

P. A. T. W. Porskamp, M. van der Leij, B. H. M. Lammerink et al. · Recueil des Travaux Chimiques des Pays-Bas · 1983 · 21 citations

, , +6