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Dehydrative Cyclization of Alkynals: Vinylidene Complexes with the C<sub>β</sub> Incorporated into Unsaturated Five‐ or Six‐Membered Rings
25
Citations
48
References
2011
Year
Vinylidene ComplexesEngineeringHeterocyclicAlkene MetathesisRhodium PrecursorsOrganic ChemistryOrganometallic CatalysisMain Group ChemistryChemistryNice RingSix‐membered RingsEnantioselective SynthesisBiomolecular EngineeringDehydrative Cyclization
A nice ring: The title compounds are easily prepared by dehydrative cyclization of terminal alkynals in the presence of osmium, iridium, and rhodium precursors (see scheme).
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