Concepedia

The first Pd<sup>II</sup>complex of a non-heteroatom stabilised carbene ligand

Martin Bröring, Carsten D. Brandt, S. Stellwag

Chemical Communications · 2003 · 83 citations · 16 references

DOI

Concepts

Abstract

Di(p-tolyl)diazomethane reacts with the tripyrrinate TrpyPdOAc(F) 1 after activation with NaBAr(F) to yield the first stable Pd(II) complex 2 of a non-Arduengo type carbene ligand, which could be characterised by X-ray crystallography.

References

16

Transition-metal-catalyzed reactions of diazo compounds. 1. Cyclopropanation of double bonds

A. J. ANCIAUX, André J. Hubert, Alfred F. Noels et al. · The Journal of Organic Chemistry · 1980 · 275 citations · Full text

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Contracted and Expanded<i>meso</i>-Alkynyl Porphyrinoids:  from Triphyrin to Hexaphyrin

Alexander Krivokapić, A.R. Cowley, Harry L. Anderson · The Journal of Organic Chemistry · 2002 · 114 citations

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A New General Method for the Preparation of Metal Carbene Complexes

Mark Gandelman, Boris Rybtchinski, Nissan Ashkenazi et al. · Journal of the American Chemical Society · 2001 · 101 citations

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Carbenerhodium Complexes with Diaryl‐ and Aryl(alkyl)carbenes as Ligands: The Missing Link in the Series of the Double Bond Systems <i>trans</i>‐[RhCl{ C(C)<sub>n</sub>RR′}(L)<sub>2</sub>] Where <i>n</i> 0, 1, and 2

Peter Schwab, Norbert Mahr, Justin Wolf et al. · Angewandte Chemie International Edition in English · 1993 · 73 citations

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Double Bonds in Motion: Bis(oxazolinylmethyl)pyrroles and Their Metal‐Induced Planarization to a New Class of Rigid Chiral <i>C</i><sub>2</sub>‐symmetric Complexes

Clément Mazet, Lutz H. Gade · Chemistry - A European Journal · 2003 · 73 citations

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