Publication | Closed Access
How Hydration Drastically Improves Adsorption Selectivity for CO<sub>2</sub> over CH<sub>4</sub> in the Flexible Chromium Terephthalate MIL‐53
440
Citations
25
References
2006
Year
Carbon DioxideEngineeringHydration DrasticallyOrganic ChemistryChemistryChemical EngineeringAdsorption SelectivityMetal-organic PolyhedronMaterials ScienceInorganic ChemistryCovalent Bonded FrameworkChemisorptionPhysical ChemistryCatalysisSelectivity BindingAdsorptionMetal-organic FrameworksChemical TechnologyPorous CarbonPhysicochemical AnalysisDeep Breath
Taking a deep breath: The hydrated form of the microporous metal organic framework MIL-53(Cr) performs better than the dehydrated form for the selectivity binding of carbon dioxide over methane (see graph). The polarity of the adsorbed gas is thought to play a role in inducing framework flexibility and the breathing of the pores.
| Year | Citations | |
|---|---|---|
Page 1
Page 1