Catalysis Science & Technology · 2011 · 69 citations · 15 references
Natural SciencesChemical EngineeringChemistryCatalysisGreen ChemistryReaction EngineeringCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MaterialsHeterogeneous CatalysisNanocatalysisCatalyst Development For SynthesisHeterogeneous Catalyst DesignNanostructured CatalystsOrganic Reaction ChemistryPalladium CatalystsTransition Metal Catalyst Design
A new series of leach-proof nanostructured Pd(0) catalysts able to catalyze a number of fundamental organic transformations including C–C bond formation has been developed. Reactions in general proceed with high yield and often at completion, while the catalysts can be reused in further reaction runs. This establishes a new class of relevant solid catalysts for synthetic organic chemistry trademarked SiliaCat Pd0 Hydrogel.
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Ligand-free Heck reactions using low Pd-loading
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