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ESR STUDY OF CATION RADICALS OF SILYL-SUBSTITUTED ETHERS AND SULFIDES
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1986
Year
Chemical EngineeringEngineeringPhysicsNatural SciencesRadical (Chemistry)Chemical BondSpectra-structure CorrelationNonbonding OrbitalsOrganic ChemistryPhysical ChemistryQuantum ChemistryChemistryOccupied Molecular OrbitalMolecular ChemistryCation Radicals
Abstract ESR spectra of cation radicals of trialkylsilyl-substituted ethers and sulfides have provided an experimental measure of the mixing between a silicon–carbon σ bonding orbital and a nonbonding orbitals on oxygen and sulfur atoms in the singly occupied molecular orbital.
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