Chemical Communications · 2009 · 168 citations · 30 references
Natural SciencesChemistryMaterials ScienceElectrochemistrySurface ChemistrySurface ScienceElectroanalytical ChemistryElectrochemical SynthesisElectrode KineticsElectrode MaterialsRedox-active MaterialsSurface ReactivityCarbon ElectrodesElectrocatalytic Surface ReactionsElectrode InterfacesElectrode Surface StructureElectrode WettabilityGlassy Carbon ElectrodesHydrogen EvolutionHydrogen Evolution Reaction
Aryl-substituted tetraimine complexes related to Co(dmgBF(2))(2)(MeCN)(2) (dmg = dimethylglyoxime) were synthesized and are active for hydrogen evolution. Co(dmgBF(2))(2)(MeCN)(2) can be adsorbed to a glassy carbon electrode. The chemically modified electrode is active for hydrogen evolution in aqueous solution at pH < 4.5, with an overpotential of only 100 mV.
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Synthesis of the H-cluster framework of iron-only hydrogenase
Cédric Tard, Xiaoming Liu, Saad K. Ibrahim et al. · Nature · 2005 · 505 citations