Concepedia

Phospha-alkynes - Useful Building Blocks in Organic Chemistry<sup>1</sup>

Manfred Regitz, Wolfgang Rösch, Thomas Allspach, U. ANNEN, Karsten Blatter, Jürgen Fink, M. HERMESDORF, H. Heydt, U.‐J. VOGELBACHER, Oliver Wagner

Phosphorous and Sulfur and the Related Elements · 1987 · 24 citations · 3 references

DOI

Concepts

Abstract

Abstract The syntheses of phospholes (7, [3+2]-cycloaddition), bicyclophosphaalkenes (17, [4+2]-cycloaddition), and phosphabenzenes (15, [4+2]-cycloaddition followed by an extrusion process) starting from the phosphaalkynes (4) are described. The 2–Dewar phosphabenzene 18, obtained from the cyclobutadiene 21 and 4 (R =tBu), is the starting material for the synthesis of the valency isomers 19, 20, 22, and 23.

References

3

Acyl-und Alkylidenphosphane, XV 2.2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl 1/ Acyl- and Alkylidenephosphines, XV 2,2-Dimethylpropvlidynephosphine, a Stable Compound with a Phosphorus Atom of Coordination Number 1

Gerd Becker, Gudrun Gresser, Werner Uhl · Zeitschrift für Naturforschung B · 1981 · 393 citations · Full text

, , +9

Unusually Coordinated Phosphorus Compounds; 7<sup>1</sup>. Adamant-1-ylmethylidynephosphine, A New, Stable Phosphaalkyne

Thomas Allspach, Manfred Regitz, G. Becker et al. · Synthesis · 1986 · 126 citations

, , +7

Notizen: Phosphorverbindungen ungewöhnlicher Koordination, 12. Diels-Alder-Reaktionen mit <sup>t</sup>Bu–C ≡ P – ein ergiebiger Weg zu λ<sub>3</sub>-Phosphininen/ Phosphorus Compounds with Unusual Coordination, 12. Diels-Alder Reactions with <sup>t</sup>B u–C≡ P–a Lucrative Access to λ<sup>3</sup>-Phosphinines

Wolfgang Rösch, Manfred Regitz · Zeitschrift für Naturforschung B · 1986 · 61 citations · Full text

, , +4