Publication | Closed Access
C<sub>8</sub> and C<sub>12</sub> sp Carbon Chains That Span Two Platinum Atoms: The First Structurally Characterized 1,3,5,7,9,11-Hexayne
100
Citations
12
References
1999
Year
Reaction SequencesEngineeringFirst Structurally CharacterizedMolecular BiologyChemistryCx Complexes TransLinear Chain CompoundInorganic CompoundSpan TwoStructure ElucidationInorganic ChemistryPlatinum AtomsCrystallographyInorganic SynthesisBiomolecular EngineeringNatural SciencesCoordination ComplexMolecular ComplexMain Group ChemistryOxidative ⋮Ch/hc⋮ Cross-Metal Chain Compound
Reaction sequences involving trans-(p-tol)(Ar3P)2PtCl (Ar = Ph, p-tol), HC⋮CC⋮CH, HC⋮CSiEt3, and oxidative ⋮CH/HC⋮ cross- or homocoupling (O2, cat. CuCl/TMEDA) give the Cx complexes trans,trans-(p-tol)(Ar3P)2Pt(C⋮C)nPt(PAr3)2(p-tol) (n = 4, 6), which have been characterized by crystallography and by IR, NMR, and UV−visible spectroscopy.
| Year | Citations | |
|---|---|---|
Page 1
Page 1