Design and Formation of a Large Tetrahedral Cluster Using 1,1′‐Binaphthyl Ligands

Abstract

Greater than 700 Å3 is the calculated interior volume of a novel [Ga4L6] cluster constructed with a derivatized 1,1′-binaphthyl ligand. Due to the size of the cavity, a guest molecule of suitable size and shape is employed to template the supramolecular assembly (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z801226_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.