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[(AsOH)<sub>3</sub>(MoO<sub>3</sub>)<sub>3</sub>(AsMo<sub>9</sub>O<sub>33</sub>)]<sup>7−</sup> and [(AsOH)<sub>6</sub>(MoO<sub>3</sub>)<sub>2</sub>(O<sub>2</sub>MoOMoO<sub>2</sub>)<sub>2</sub>‐(AsMo<sub>9</sub>O<sub>33</sub>)<sub>2</sub>]<sup>10−</sup>: Coupling of Highly Negatively Charged Building Blocks

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Citations

4

References

1996

Year

Abstract

For the directed synthesis of polyoxometalates the linking of the heteropolyanion 1 (schematic representation shown on the right) to form the dimeric anion 2 is extremely significant. The formation of the corresponding potassium salts of 1 and 2 from K2MoO4 and As2O3 is controlled merely by the pH value of the solution.

References

YearCitations

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