Publication | Closed Access
A Functionalized Ag<sub>2</sub>S Molecular Architecture: Facile Assembly of the Atomically Precise Ferrocene‐Decorated Nanocluster [Ag<sub>74</sub>S<sub>19</sub>(dppp)<sub>6</sub>(fc(C{O}OCH<sub>2</sub>CH<sub>2</sub>S)<sub>2</sub>)<sub>18</sub>]
66
Citations
45
References
2015
Year
Materials ScienceInorganic ChemistryEngineeringNanoclusterNanomaterialsNanotechnologyOrganic ChemistryOrganometallic CatalysisFacile AssemblyChemistryGood YieldFunctional MaterialsInorganic SynthesisNanoarchitectonics
A ferrocene-based dithiol 1,1'-[fc(C{O}OCH2CH2SH)2] has been prepared and treated with a Ag(I) salt to form the stable dithiolate compound [fc(C{O}OCH2CH2SAg)2]n (fc=[Fe(η(5)-C5H4)2]). This is used as a reagent for the preparation of the nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18] which was obtained in good yield (dppp=1,3-bis(diphenylphosphino)propane).
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