Journal of The Electrochemical Society · 1985 · 247 citations · 0 references
EngineeringChemical EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryMembrane ScienceComposite MembranesMembrane EngineeringMembrane MaterialsMembrane PermeabilitySolid ElectrolytesSolid-state ElectrolytesComposite Ion-exchange MembranesGas PermeationMembrane PerformanceMembrane ThicknessMembrane Thickness EffectsPolymer Electrolyte MembranesWater ElectrolysisWater Electrolysis Membranes
The study examined gas permeation in Nafion membranes and composites under varying conditions. Permeability of Nafion varied with water content, cation form, ion‑exchange capacity, temperature, pressure, and thickness, with hydrogen permeating roughly twice as fast as oxygen, and the catalyst layer structure influencing gas transport during electrolysis.
Gas permeation properties for Nafion membranes and their composites were investigated under various conditions. The permeability coefficients of Nafion depended greatly on the water content, the cation form, and the ion‐exchange capacity. The gas permeation rate through a same sample varied with temperature, pressure, and membrane thickness. The permeabilty of hydrogen was about twice as great as that of oxygen. The electrocatalyst plated on the membrane did not serve as a barrier for gas permeation, but the structure of the catalyst layer played an important role in gas permeation during water electrolysis.