Concepedia

An Improved Procedure for the Cr(II) Mediated Homoallylic Alcohol Synthesis

Peter G. M. Wuts, Gary R. Callen

Synthetic Communications · 1986 · 18 citations · 6 references

DOI

Concepts

Abstract

Abstract An improved procedure was developed for the coupling of allylhalides with aldehydes which utilizes CrCl2 prepared by reduction of CrCl3 with sodium amalgam.

References

6

Grignard-type carbonyl addition of allyl halides by means of chromous salt. A chemospecific synthesis of homoallyl alcohols

Yoshitaka Okude, S. HIRANO, Tamejiro Hiyama et al. · Journal of the American Chemical Society · 1977 · 512 citations

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Further synthetic studies on rifamycin s

Hiroto Nagaoka, Yoshito Kishi · Tetrahedron · 1981 · 374 citations

, , +7

Acyclic stereoselection. III. Synthesis of threo-3-hydroxy-2-methylcarboxylic acids

Charles T. Buse, Clayton H. Heathcock · Tetrahedron Letters · 1978 · 99 citations

, , +3

Further studies on chromium(II)-mediated homoallylic alcohol syntheses

Michael D. Lewis, Yoshito Kishi · Tetrahedron Letters · 1982 · 63 citations

, , +3

Total synthesis of (.+-.)-fortamine and (.+-.)-2-deoxyfortamine

Spencer Knapp, Mark J. Sebastian, H. Ramanathan · The Journal of Organic Chemistry · 1983 · 50 citations

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