Concepedia

Synthesis, Structure, and Oxidation of Donor‐Stabilized Gallium(<scp>I</scp>) Iodide: Ga<sub>8</sub>I<sub>8</sub>·6PEt<sub>3</sub>

C. Doriat, M. Friesen, E. Baum, Achim Ecker, Hansgeorg Schnöckel

Angewandte Chemie International Edition in English · 1997 · 50 citations · 19 references

DOI

Concepts

Abstract

Merely the illusion of a GaGa bond is given between the doubly I-bridged atoms of the nearly planar eight-membered ring in Ga8I8 · 6 PEt3 (shown on the right). This finding is remarkable, since the corresponding AlI halides have four-membered Al rings. D = PEt3.

References

19

Phase annealing in SHELX-90: direct methods for larger structures

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Aluminum(<scp>I</scp>) and Gallium(<scp>I</scp>) Compounds: Syntheses, Structures, and Reactions

Carsten Dohmeier, Dagmar Loos, Hansgeorg Schnöckel · Angewandte Chemie International Edition in English · 1996 · 351 citations

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[Ga<sub>4</sub>{C(SiMe<sub>3</sub>)<sub>3</sub>}<sub>4</sub>] with a Tetrahedral Ga<sub>4</sub> Skeleton

Werner Uhl, Wolfgang Hiller, Marcus Layh et al. · Angewandte Chemie International Edition in English · 1992 · 170 citations

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New synthetic pathways into the organometallic chemistry of gallium

Malcolm L. H. Green, Philip Mountford, Geoffrey J. Smout et al. · Polyhedron · 1990 · 157 citations

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