Concepedia

Grignard reagents in ionic liquids

Man Chun Law, Kwok‐Yin Wong, Tak Hang Chan

Chemical Communications · 2006 · 36 citations · 18 references

DOI

Concepts

Abstract

Grignard reagents were generated from magnesium and organic iodides in the ionic liquid n-butylpyridinium tetrafluoroborate, [bpy][BF4], and they showed different reactivity from classical Grignard reagents in organic solvents.

References

18

Organic syntheses using indium-mediated and catalyzed reactions in aqueous media

Chao‐Jun Li, Tak Hang Chan · Tetrahedron · 1999 · 519 citations

, , +11

Allylzinc reagents additions in aqueous media

Christian Pétrier, Jean Louis Luche · The Journal of Organic Chemistry · 1985 · 287 citations

, , +6

Magnesium-Mediated Carbon−Carbon Bond Formation in Aqueous Media:  Barbier−Grignard Allylation and Pinacol Coupling of Aldehydes

Wen‐Chun Zhang, Chao‐Jun Li · The Journal of Organic Chemistry · 1999 · 152 citations

, , +12

THE REDUCING ACTION OF A MIXTURE OF MAGNESIUM IODIDE (OR BROMIDE) AND MAGNESIUM ON AROMATIC KETONES. PROBABLE FORMATION OF MAGNESIUM SUBIODIDE (OR SUBBROMIDE)

M. Gomberg, W. E. Bachmann · Journal of the American Chemical Society · 1927 · 134 citations

, , +5

Activated metals. I. Preparation of highly reactive magnesium metal

Reuben D. Rieke, Phillip M. Hudnall · Journal of the American Chemical Society · 1972 · 133 citations

, , +6