Publication | Closed Access
Suzuki‐Coupling of Cp<sup>*</sup>Ru(<i>para</i>‐C<sub>6</sub>H<sub>4</sub>Br<sub>2</sub>) with Phenyl Boronic Acid: A Model Reaction for the Synthesis of Organometallic Polymers
14
Citations
15
References
1996
Year
Inorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringModel ReactionSuzuki CouplingOrganometallic PolymersOrganometallic CatalysisChemistryPhenyl Boronic AcidProduct 3Organometallic PolymerDerivative (Chemistry)Synthetic ChemistryPolymer ChemistryBiomolecular EngineeringPolymers
Abstract The synthesis of a terphenyl derivative complexed by the cationic moiety Cp * Ru + by Suzuki coupling of [Cp * Ru(BrC 6 H 4 Br)]OTf with phenyl boronic acid under catalysis of Pd(PPh 3 ) 4 in a DME‐water mixture at 85°C in quantitative yield is reported. The stable coupling product 3 was characterized by X‐ray crystal structure analysis.
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