Molecular‐Mechanical Switch‐Based Solid‐State Electrochromic Devices

David W. Steuerman, Hsian‐Rong Tseng, Andrea J. Peters, Amar H. Flood, Jan O. Jeppesen, Kent A. Nielsen, J. Fraser Stoddart, James R. Heath

Angewandte Chemie International Edition · 2004 · 226 citations · 46 references

Concepts

Abstract

You only need eyes to appreciate the color change that occurs in a polymer matrix when the bistable rotaxane shown is switched between its ground-state (green) and metastable-state (red) co-conformers. Not only is an electrochromic device within reach, but a universal switching mechanism seems to be on the cards.

References

46