Angewandte Chemie International Edition · 2004 · 226 citations · 46 references
Natural SciencesMaterials SciencePhysicsElectrochemistryElectronic MaterialsPolymer ChemistryConductive PolymersElectrochromic MaterialsElectrochromic DevicesElectrochromic Switching MechanismsMolecular SwitchesPolymer Electrochromic Materials
You only need eyes to appreciate the color change that occurs in a polymer matrix when the bistable rotaxane shown is switched between its ground-state (green) and metastable-state (red) co-conformers. Not only is an electrochromic device within reach, but a universal switching mechanism seems to be on the cards.
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Brownian motion in a field of force and the diffusion model of chemical reactions
H. A. Kramers · Physica · 1940 · 8.6K citations
Natural Sciences, Chemistry, Physics +16
A [2]Catenane-Based Solid State Electronically Reconfigurable Switch
C. Patrick Collier, Gunter Mattersteig, Eric W. M. Wong et al. · Science · 2000 · 1.4K citations
A chemically and electrochemically switchable molecular shuttle
Richard A. Bissell, Emilio Córdova, Angel E. Kaifer et al. · Nature · 1994 · 1.2K citations
Dynamical effects in electron transfer reactions
Hitoshi Sumi, R. A. Marcus · The Journal of Chemical Physics · 1986 · 946 citations
Natural Sciences, Chemistry, Physics +17