Angewandte Chemie International Edition · 2007 · 45 citations · 10 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistrySolidificationCrystallization ProcessesGelsCrystal Chemistry Of SilicatesGel PhaseMicroporous MaterialsPorous SilicaSilica-based MaterialsSilicate ChemistrySilicate Crystal Structures
Hot and steamy cages: The gel composition for MCM-68 typically obtained by hydrothermal methods is changed by steam-assisted crystallization and results in the formation of the highly crystalline pure silica analogue YNU-2P (see picture). The crystal structure of this compound indicates the presence of significant site defects.
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Conversion of dry gel to microporous crystals in gas phase
Masahiko Matsukata, Masaru Ogura, Takayuki Osaki et al. · Topics in Catalysis · 1999 · 293 citations