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A polyoxometalate-based manganese carboxylate cluster
122
Citations
20
References
2008
Year
Materials ScienceInorganic ChemistryCluster ScienceEngineeringHigh Oxidation StateStraightforward RouteSingle-atom CatalystCeiv Mniv 6Cluster ChemistryCatalysisRedox ChemistryChemistryMetal-organic PolyhedronInorganic MaterialFunctional Materials
The functionalization of a pre-formed, high oxidation state {CeIV MnIV 6} cluster with a lacunary phosphotungstate, [alpha-P2 W15 O 56]12-, exemplifies a straightforward route for grafting redox-active building blocks to existing Mn-carboxylate clusters and modeling their deposition onto metal oxide surfaces.
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