Responsive Supramolecular Polymers Based on the Bis[alkynylplatinum(II)] Terpyridine Molecular Tweezer/Arene Recognition Motif

Abstract

Supramolecular polymers are constructed based on the novel bis[alkynylplatinum(II)] terpyridine molecular tweezer/pyrene recognition motif. Successive addition of anthracene as the diene and cyano-functionalized dienophile triggers the reversible supramolecular polymerization process, thus advancing the concept of utilizing Diels-Alder chemistry to access stimuli-responsive materials in compartmentalized systems.