Physical Chemistry Chemical Physics · 2012 · 53 citations · 56 references
EngineeringHybrid CapacitorChemistryChemical EngineeringPorous Cuo NanobeltsMaterials ScienceIntegrated ElectrodeElectrochemical Power SourceSurface ElectrochemistryLithium-ion BatteriesEnergy StorageUnique Nanostructural FeaturesElectrochemical CellElectrochemical ProcessElectrochemical Double Layer CapacitorElectrochemistryCu SubstrateNanomaterialsLi-ion Battery MaterialsHigh Electrochemical PerformanceElectrochemical Energy StorageBatteries
A facile and low-cost approach has been developed to fabricate porous CuO nanobelts directly grown on a Cu substrate. The as-prepared CuO samples can be directly used as integrated electrodes for lithium-ion batteries and pseudo-supercapacitors without the addition of other ancillary materials such as carbon black or a binder to enhance electrode conductivity and cycling stability. The unique nanostructural features endow them with excellent electrochemical performance as demonstrated by high capacities of 640 mA h g(-1) after 100 cycles at 0.2 C rate and an excellent specific capacitance of 340 F g(-1), which corresponds to the energy density of 45 W h kg(-1). The cyclability of the electrode demonstrates only a 10-15% loss in capacitance over 5000 cycles.
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