Concepedia

A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d<sup>10</sup>coinage metals

Pengfei Ai, Andreas A. Danopoulos, Pierre Braunstein, Kirill Yu. Monakhov

Chemical Communications · 2013 · 84 citations · 28 references

DOI

Concepts

Abstract

A novel N,N'-diphosphanyl-imidazol-2-ylidene acts as a stable, hybrid PC(NHC)P ligand for M2 or linear M3 (M = Cu, Ag, Au) arrays with metallophilic interactions.

References

28

Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands

Matthias Scholl, Sheng Ding, Choon Woo Lee et al. · Organic Letters · 1999 · 3.4K citations

, , +15

Heterocyclic Carbenes: A High‐Yielding Synthesis of Novel, Functionalized N‐Heterocyclic Carbenes in Liquid Ammonia

Wolfgang A. Herrmann, Christian Köcher, Lukas J. Gooßen et al. · Chemistry - A European Journal · 1996 · 347 citations

, , +8

Stable N-functionalised ‘pincer’ bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies

Andreas A. Danopoulos, S. Winston, William B. Motherwell · Chemical Communications · 2002 · 216 citations

, , +15

Synthesis and Characterization of<i>N</i>-Heterocyclic Carbene Phospha-Palladacycles and Their Properties in Heck Catalysis

Guido D. Frey, Jan Schütz, Eberhardt Herdtweck et al. · Organometallics · 2005 · 182 citations

, , +15

On C−C Coupling by Carbene-Stabilized Palladium Catalysts:  A Density Functional Study of the Heck Reaction

Katrin Albert, Philip Gisdakis, Notker Rösch · Organometallics · 1998 · 155 citations

, , +15