Angewandte Chemie International Edition · 2003 · 268 citations · 12 references
Natural SciencesMaterials EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryEnergy MaterialsAnode MaterialsBattery MaterialsBattery SystemsCarbon-based Energy MaterialsElectrochemical CellsElectrode MaterialsCarbon For Lithium-ion BatteriesCarbon-based AnodesGraphite AnodesLithium-ion Batteries
Lithium-ion batteries are the most convenient form of electrical storage. But their natural-graphite anodes are not compatible with propylene carbonate-based electrolytes. The edge planes of the graphite are attacked by the electrolyte, whereas the basal planes remain inert. A technique can be applied to form spherical graphite particles, which maximize the basal-plane exposure while the edge planes remain hidden (see picture). Thus only a small amount of carbon coating is now needed to protect the graphite core from the electrolyte.
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Doron Aurbach, Yair Ein‐Eli, Orit Chusid et al. · Journal of The Electrochemical Society · 1994 · 456 citations