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Axially Chiral <i>C</i><sub>2</sub>‐Symmetric <i>N</i>‐Heterocyclic Carbene (NHC) Palladium Complex‐Catalyzed Asymmetric Fluorination and Amination of Oxindoles
28
Citations
53
References
2012
Year
Chemical EngineeringEnantioselective Asymmetric FluorinationEngineeringModerate EnantioselectivitiesCross-coupling ReactionEffective CatalystOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHeterocycle ChemistryAsymmetric CatalysisEnantioselective Synthesis
Abstract Chiral C 2 ‐symmetric N ‐heterocyclic carbene (NHC) palladium diaquo complex 5b prepared from ( S )‐BINAM was found to be a fairly effective catalyst for the enantioselective asymmetric fluorination of oxindoles to give the corresponding products in moderate enantioselectivities along with good to excellent yields.
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