Die Makromolekulare Chemie · 1973 · 10 citations · 15 references
Natural SciencesChemical EngineeringChemistryPhysical ChemistryPolymer ChemistryThermodynamicsPolymer Physical ChemistryPolymer PhysicsPolymer StructurePolymer ThermodynamicsPolymerization ChemistryPolymerization ProcessesAmorphous Polymer StructureEnthalpy Of PolymerizationPolymer Amorphous Phase BehaviorPolymerization ThermodynamicsTemperature Dependence Of PolymerizationThermodynamic MeasurementsThermodynamic Modeling
Abstract The equilibrium between gaseous monomer and amorphous polymer has been studied for oxepane and 1,3‐dioxepane between 38°C and 92°C. From the equilibrium pressures of monomer the Δ H ° gc and Δ S ° gc values have been calculated. Thermodynamic data for the vaporisation of each monomer have also been measured and have enabled values of Δ H 1c ° and Δ S 1c ° for the polymerisations to be calculated. For oxepane: and for 1,3‐dioxepane:
15
Robert D. Stolow · Journal of the American Chemical Society · 1966 · 710 citations
Thermodynamic functions of linear high polymersPart I—polyoxymethylene
F. S. Dainton, Deborah G. Evans, F. E. Hoare et al. · Polymer · 1962 · 179 citations