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ORGANIC SYNTHESIS USING HALOBORATION REACTION. IV. IODOBORAXION REACTION OF TERMINAL ALLENES
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1984
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Chemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisCorresponding 2-IodoalkenesOrganic ChemistryOrganometallic CatalysisChemistryAbstract Terminal AllenesHalogenationEnantioselective SynthesisBiomolecular EngineeringAcetic Acid
Abstract Terminal allenes react smoothly with B-iodo-9-borabicyclo[3.3.1]nonane (B-iodo-9-BBN), and the subsequent protonolysis with acetic acid gives the corresponding 2-iodoalkenes.
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