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Properties of polyamide-based catalysts. Part I. Hydrodehalogenation of chlorobenzene
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1975
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Chemical EngineeringEngineeringConventional Ai2o3-based CatalystsPolyamide-based CatalystsOrganic ChemistryCatalysisMolecular CatalysisChemistryHomogeneous CatalysisCatalyst PreparationPhci DecreasePalladium–poly-p-phenyleneterephthalamide CatalystsPolymer ChemistryCatalytic Synthesis
The activities and selectivities of platinum–, rhodium–, and palladium–poly-p-phenyleneterephthalamide catalysts were compared for the hydrodehalogenation of chlorobenzene, and differences in reactivity with respect to conventional AI2O3-based catalysts were disclosed. Conversions of PhCI decrease in the order Pd > Rh > Pt. A reaction mechanism is proposed to interpret the results.