Use of achiral additives to increase the stereoselectivity in Rh(ii)-catalyzed cyclopropanations - Concepedia

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Use of achiral additives to increase the stereoselectivity in Rh(ii)-catalyzed cyclopropanations

41

Citations

29

References

2010

Year

David Marcoux, Vincent N. G. Lindsay, André B. Charette

Chemical Communications

Chemical EngineeringEngineeringAlkene MetathesisBiochemistryNatural SciencesBrønsted AcidsOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryAchiral AdditivesVarious Lewis BasesAsymmetric Catalysis

Abstract

We describe our studies on the effect of various Lewis bases and Brønsted acids as achiral additives on the stereoselectivity of some Rh(ii)-catalyzed cyclopropanations.

References

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