Journal of Polymer Science Polymer Chemistry Edition · 1981 · 14 citations · 11 references
Natural SciencesChemical EngineeringChemistryPolymer ChemistryPolymer EngineeringThermodynamicsDegradation ProductsPolymer DegradationPolymer Physical ChemistryPolymer ProcessingPolymer ThermodynamicsThermogravimetric AnalysisActivation EnergyHeating Rate EffectsPolymer Degradation KineticsPolymer Degradation MechanismsPolymer Thermal DegradationThermal StabilityThermal Stability Of PolymersThermogravimetric Curves
Abstract The influence of the degree of hydrolysis on thermoxidative degradation of the poly(vinyl alcohol) was studied. The thermoxidative degradation was carried out under dynamic thermal conditions. Taking into account the dependence of the activation energy values on the heating rate, molecular weight, degree of conversion, and degree of hydrolysis, some conclusions were drawn about the decomposition mechanism and the variation of the thermal stability.
11
Kinetic Parameters from Thermogravimetric Data
A. W. Coats, J. P. Redfern · Nature · 1964 · 6.8K citations
Poly(vinyl alcohol) properties and applications