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Desymmetrization of <i>meso</i>‐Bicyclic Hydrazines by Rhodium‐Catalyzed Enantioselective Hydroformylation
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Citations
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References
2008
Year
Chemical EngineeringFormyl ProductEngineeringAsymmetric HydroformylationOrganic ChemistryOrganometallic CatalysisCatalysisSynthetic ChemistryChemistryAsymmetric CatalysisRhodium‐catalyzed Enantioselective HydroformylationEnantioselective SynthesisHydroxymethyl Hydrazines
Abstract An asymmetric hydroformylation of three meso ‐bicyclic hydrazines followed by the reduction of the formyl product afforded the corresponding desymmetrized optically enriched hydroxymethyl hydrazines (up to 77.5 % ee ). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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