Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃]

Abstract

Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.