Publication | Open Access
Versatile Supramolecular Copper(II) Complexes for Henry and Aza‐Henry Reactions
92
Citations
50
References
2009
Year
EngineeringOrganic ChemistryAromatic IminesChemistryInorganic CompoundChemical EngineeringOrganometallic CatalysisMetal-organic PolyhedronInorganic ChemistryDiversity-oriented SynthesisCopper ComplexesCatalysisAsymmetric CatalysisVersatile Supramolecular CopperInorganic SynthesisEnantioselective SynthesisNatural SciencesCoordination ComplexHigh Yield
Abstract magnified image Chiral supramolecular metal‐organic frameworks assembled from copper complexes catalyse Henry and aza‐Henry reactions of aromatic and aliphatic aldehydes and N ‐protected aromatic imines in high yield and good to excellent enantioselectivity. Reactions can be performed in the absence of base in ethanol or water.
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