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Elucidating the intercalation mechanism of zinc ions into α-MnO<sub>2</sub> for rechargeable zinc batteries
523
Citations
32
References
2015
Year
EngineeringChemistryChemical EngineeringSodium BatteryMaterials ScienceInorganic ChemistryElectrical EngineeringBattery Electrode MaterialsAdvanced Electrode MaterialRechargeable Zinc BatteriesEnergy StorageZinc IonsIntercalation MechanismElectrochemistryElectric BatteryLayered CompoundLi-ion Battery MaterialsInterlayer SpacingCathode MaterialsElectrochemical Energy StorageBatteries
The intercalation mechanism of zinc ions into 2 × 2 tunnels of an α-MnO2 cathode for rechargeable zinc batteries was revealed. It involves a series of single and two-phase reaction steps and produces buserite, a layered compound with an interlayer spacing of 11 Å as a discharge product.
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