Concepedia

Oxidation of Unactivated Primary Aliphatic Amines Catalyzed by an Electrogenerated 3,4‐Azaquinone Species: A Small‐Molecule Mimic of Amine Oxidases

Martine Largeron, Anne Neudörffer, Maurice‐Bernard Fleury

Angewandte Chemie International Edition · 2003 · 58 citations · 22 references

DOIFull text

Open access

Concepts

Abstract

High catalytic performance of the electrogenerated amine oxidase mimic 3,4-iminoquinone 1ox is observed under metal-free conditions in the chemoselective oxidation reaction of unactivated primary aliphatic amines.

References

22

Oxygen Binding, Activation, and Reduction to Water by Copper Proteins

Edward I. Solomon, Peng Chen, Markus Metz et al. · Angewandte Chemie International Edition · 2001 · 830 citations

, , +12

Catalytic Mechanism of the Topa Quinone Containing Copper Amine Oxidases

Minae Mure, Stephen A. Mills, Judith P. Klinman · Biochemistry · 2002 · 227 citations

, , +12

Synthesis and spectroscopic characterization of model compounds for the active site cofactor in copper amine oxidases

Minae Mure, Judith P. Klinman · Journal of the American Chemical Society · 1993 · 131 citations

, , +13

Model Studies of Topaquinone-Dependent Amine Oxidases. 2. Characterization of Reaction Intermediates and Mechanism

Minae Mure, Judith P. Klinman · Journal of the American Chemical Society · 1995 · 101 citations

, , +12

Evidence Against Reduction of Cu<sup>2+</sup> to Cu<sup>+</sup> during Dioxygen Activation in a Copper Amine Oxidase from Yeast

Stephen A. Mills, Judith P. Klinman · Journal of the American Chemical Society · 2000 · 79 citations

, , +16