Publication | Closed Access
The solvent effect in an axially symmetric Fe<sup>III</sup><sub>4</sub> single-molecule magnet
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Citations
19
References
2014
Year
Magnetic PropertiesEngineeringLow-dimensional MagnetismMagnetic ResonanceSolvent EffectAxial SymmetryChemistryMagnetic MaterialsFerrofluidMagnetismEnantiopure FeQuantum MaterialsMolecular MagnetismInorganic ChemistryMaterials SciencePhysicsPhysical ChemistryMagnetic MaterialCrystallographySpintronicsFerromagnetismDisordered Solvent MoleculesMolecule-based MagnetNatural SciencesCondensed Matter PhysicsApplied PhysicsMagnetic Property
A pair of enantiopure Fe(III)4 SMMs with axial symmetry was synthesized and characterized by magnetization and high-frequency electron paramagnetic resonance methods. The results reveal that the axial symmetry of the structure is broken by the interaction of Fe(III)4 with the disordered solvent molecules.
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