Detection of explosives using a hollow cathode discharge ion source

Abstract

Because the major NOx(-) ions (x = 2, 3) produced in the plasma act as reagent ions in ion-molecule reactions of explosives, air is best suited as a carrier gas for the detection of explosives. It is proposed that the NOx(-) (x = 2, 3) and O3 contributed to the formation of [TNT-H](-) and [TNT-NO](-) ions, via the reactions NOx(-) + TNT → [TNT-H](-) + HNOx and [TNT](-) + O3 → [TNT-NO](-) + NO2 + O2.