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KHSO4: a catalyst for the chemo-selective preparation of 1,1-diacetates from aldehydes under solvent-free conditions
44
Citations
33
References
2005
Year
Chemical EngineeringNovel OrganocatalystsAromatic AldehydesPotassium Hydrogen SulfateEngineeringGreen ChemistryCatalytic SynthesisOrganic ChemistrySolvent-free ConditionsCatalysisHomogeneous CatalysisChemistryChemo-selective PreparationGreen MethodMolecular CatalysisAsymmetric CatalysisSynthetic ChemistryBiomolecular Engineering
A simple, mild, effective and green method to form acylals from aliphatic and aromatic aldehydes in good to excellent yields in the presence of potassium hydrogen sulfate, KHSO4, as catalyst under solvent-free conditions is described. Ketones are not affected under the reaction conditions.
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