Publication | Closed Access
<i>meso</i>‐(Tetraphenylporphinato)manganese(<scp>III</scp>)‐tetracyanoethenide, [Mn<sup>III</sup>TPP]<sup>::⊕</sup>[TCNE]<sup>.⊖</sup>. A New Structure‐Type Linear‐Chain Magnet with a T<sub>c</sub> of 18K
202
Citations
16
References
1992
Year
Magnetic PropertiesEngineeringLow-dimensional MagnetismMagnetic ResonanceChemistryMagnetic MaterialsMagnetismNew MaterialQuantum MaterialsMaterials ScienceInorganic ChemistryMolecular MagnetismMolecular SolidPhysicsMolecular MaterialMolecular MaterialsMagnetic MaterialRoom TemperatureFerromagnetismMolecule-based MagnetNatural SciencesMagnetic PropertyMolecule-based MaterialFunctional MaterialsMetal Chain Compound
Cooperative magnetic interactions in molecular materials at room temperature are the goal of much interdisciplinary research. The title compound is shown to have a T c of 18 K and to be of a new structural type which makes it a suitable model for the previously reported, disordered, infusible V(TCNE), which is a room‐temperature magnet. The synthesis and structure of the new material are discussed.
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