Publication | Closed Access
A Stereoselective Synthesis of (±) Exobrevicomin; Synthetic Applications of Gamma-Alkoxy Allylboronates
15
Citations
2
References
1982
Year
Gamma-alkoxy AllylboronateEngineeringGamma-alkoxy AllylboronatesNatural SciencesDiversity-oriented SynthesisKeto Diol PrecursorsOrganic ChemistryStereoselective SynthesisChemistrySynthetic ApplicationsPharmacologyAsymmetric CatalysisEnantioselective SynthesisBiomolecular EngineeringBicyclic AcetalNatural Product Synthesis
Abstract A synthesis of the naturally occurring bicyclic acetal, “exobrevicomin” is described. The requisite threo stereochemistry of keto diol precursors is obtained selectively by condensation of a gamma-alkoxy allylboronate with an appropriate aldehyde.
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