Sensitivity analysis of the 2-methylpyridine N-oxidation kinetic model

Abstract

A sensitivity analysis of a previously developed global kinetic model, of the N-oxidation of 2-methylpyridine, involving seven kinetic and equilibrium constants, has been performed. It has been identified how individual constants influence the power evolution profile. The conditions, which ensure measurements sensitive to all constants, are outlined. A readily applicable, simple methodology has been developed to achieve accurate evaluation of the kinetic constants involved.