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Unprecedented stereoselectivity in the addition of organoiron(II) reagents to cyclohexanone derivatives
20
Citations
9
References
1993
Year
EngineeringHeterocyclicCyclohexanone DerivativesOrganic ChemistryOrganometallic CatalysisStereoselective SynthesisChemistryEquatorial DirectionVarious OrganoironEnantioselective SynthesisBiomolecular Engineering
Various organoiron(II) reagents undergo Grignard-type additions to substituted cyclohexanone derivatives, C–C bond formation occurring stereoselectively from the equatorial direction (97–100% selectivity).
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