Concepedia

Dialkylborane-Catalyzed Hydroboration of Alkynes with 1,3,2-Benzodioxaborole in Tetrahydrofuran

Akira Arase, M. HOSHI, Akihiko Mijin, Kohei Nishi

Synthetic Communications · 1995 · 58 citations · 11 references

DOI

Concepts

Abstract

Abstract Dialkylborane catalyzed hydroboration of alkynes with an equimolar amount of 1,3,2-benzodioxaborole in tetrahydrofuran efficiently to provide 2-alkenyl-1,3,2-benzodioxaborole under mild reaction conditions.

References

11

Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst

Norio Miyaura, Akira Suzuki · Journal of the Chemical Society Chemical Communications · 1979 · 1.2K citations

, , +8

Catalytic Hydroboration with Rhodium Complexes

Detlef Männig, Heinrich Nöth · Angewandte Chemie International Edition in English · 1985 · 499 citations

, , +7

Catecholborane (1,3,2-benzodioxaorole) as a new, general monohydroboration reagent for alkynes. Convenient synthesis of alkeneboronic esters and acids from alkynes via hydroboration

Herbert C. Brown, S. K. GUPTA · Journal of the American Chemical Society · 1972 · 231 citations

, , +5

Hydroboration. XXXIX. 1,3,2-Benzodioxaborole (catecholborane) as a new hydroboration reagent for alkenes and alkynes. General synthesis of alkane- and alkeneboronic acids and esters via hydroboration. Directive effects in the hydroboration of alkenes and alkynes with catecholborane

Herbert C. Brown, S. K. GUPTA · Journal of the American Chemical Society · 1975 · 225 citations

, , +5

Reaction of alkenylboronic acids with iodine under the influence of base. Simple procedure for the stereospecific conversion of terminal alkynes into trans-1-alkenyl iodides via hydroboration

Herbert C. Brown, Tsutomu Hamaoka, N. RAVINDRAN · Journal of the American Chemical Society · 1973 · 160 citations

, , +8