Pyridinetrihalogenometallate anions, pyMX<sub>3</sub><sup>–</sup>, of cobalt(<scp>II</scp>), nickel(<scp>II</scp>), and zinc(<scp>II</scp>)

D.H. Brown, K. P. Forrest, R. H. Nuttall, D. W. A. Sharp

Journal of the Chemical Society A Inorganic Physical Theoretical · 1968 · 22 citations · 0 references

Concepts

Abstract

Salts containing pyMX3– and picMX2–(py = pyridine, pic =α-picoline) anions have been prepared for cobalt, nickel, and zinc (X = Cl, Br, or I). The spectra, conductivities, and magnetic susceptibilities of the salts have been studied and are in accord with the anions having a pseudo-tetrahedral structure about the metal atoms.