Concepedia

Light driven water oxidation by a single site cobalt salophen catalyst

Erica Pizzolato, Mirco Natali, Bianca Posocco, Alejandro Montellano López, Irene Bazzan, Marilena Di Valentin, Pierluca Galloni, Valeria Conte, Marcella Bonchio, Franco Scandola,

Chemical Communications · 2013 · 93 citations · 27 references

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Abstract

A salophen cobalt(II) complex enables water oxidation at neutral pH in photoactivated sacrificial cycles under visible light, thus confirming the high appeal of earth abundant single site catalysis for artificial photosynthesis.

References

27

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co <sup>2+</sup>

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Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å

Yasufumi Umena, Keisuke Kawakami, Jian‐Ren Shen et al. · Nature · 2011 · 3.9K citations · Full text

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EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH

J. Gregory McAlpin, Yogesh Surendranath, Mircea Dincă et al. · Journal of the American Chemical Society · 2010 · 539 citations · Full text

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Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles

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Electrocatalytic Water Oxidation Beginning with the Cobalt Polyoxometalate [Co<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>(PW<sub>9</sub>O<sub>34</sub>)<sub>2</sub>]<sup>10–</sup>: Identification of Heterogeneous CoO<sub><i>x</i></sub> as the Dominant Catalyst

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