Angewandte Chemie International Edition · 2015 · 84 citations · 55 references
Natural SciencesBiochemistryChemistryCatalysisPolymer ChemistryPolymer MaterialsChain-growth PolymerizationCoordination PolymersPolymer StructurePolymer SynthesisPolymerization ChemistryPolymerization ProcessesCoordination-insertion PolymerizationPolymer Adduct Formation
The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.
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