Publication | Open Access
The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet
290
Citations
28
References
2014
Year
Magnetic PropertiesEngineeringMagnetic ResonanceChemistryMagnetismFirst Near-linear BisNovel StructureMolecular MagnetismPhysicsF-block ComplexMolecular MaterialQuantum ChemistryMagnetic MaterialCrystal Structure DesignQuantum MagnetismSpintronicsMolecule-based MagnetNatural SciencesApplied PhysicsSingle Molecule MagnetMagnetic PropertyMolecule-based Material
We report the first near-linear bis(amide) 4f-block compound and show that this novel structure, if implemented with dysprosium(III), would have unprecedented single molecule magnet (SMM) properties with an energy barrier, Ueff, for reorientation of magnetization of 1800 cm(-1).
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