Concepedia

Complexes of 1,5‐Di(<i>p</i>‐tolyl)‐1,4‐pentaazadien‐3‐ide, Crystal Structures of [Cu(tolylNNNNNtolyl)]<sub>3</sub> and [Ni(tolylNNNNNtolyl)<sub>2</sub>]<sub>2</sub>

Johannes Beck, Joachim Strähle

Angewandte Chemie International Edition in English · 1985 · 110 citations · 4 references

DOI

Concepts

Abstract

Three linearly arranged Cu ⊕ ions, coordinated by three parallel N 5 zig‐zag chains in such a way that each metal ion is surrounded by a trigonal planar array of N atoms, are present in the pentaazadienide complex 1 . The red crystals of 1 exhibit weak paramagnetism; the CuCu distances in the chains are the shortest observed so far in copper( I ) complexes. equation image

References

4

The crystal structure of diazoaminobenzene copper(I)

I. D. Brown, J. D. Dunitz · Acta Crystallographica · 1961 · 92 citations · Full text

, , +13

Binuclear metal(II) complexes of 1,3-diphenyltriazene : The crystal and molecular structures of the nickel(II), palladium(II) and copper(II) derivatives

Michael J. Corbett, BF Hoskins, NJ McLeod et al. · Australian Journal of Chemistry · 1975 · 74 citations

, , +16

Synthese und Strukturuntersuchungen von Iodocupraten(I), III. Iodocuprate(I) mit isolierten Ketten <sup>1</sup> <sub>∞</sub>[Cu<sub>2</sub>I<sub>3</sub>]<sup>–</sup> bzw. <sup>1</sup> <sub>∞</sub>[Cu<sub>3</sub>I<sub>4</sub>]<sup>–</sup> [1] / Synthese und Strukturuntersuchungen von Iodocupraten(I), III. Iodocuprate(I) mit isolierten Ketten <sup>1</sup> <sub>∞</sub>[Cu<sub>2</sub>I<sub>3</sub>]<sup>–</sup> bzw. <sup>1</sup> <sub>∞</sub>[Cu<sub>3</sub>I<sub>4</sub>]<sup>–</sup>

H. Hartl, Farbod Mahdjour‐Hassan‐Abadi · Zeitschrift für Naturforschung B · 1984 · 34 citations · Full text

, , +4

The metal ammine cyanide aromatic clathrates. XIII. The crystal structure of the Hofmann-type biphenyl clathrate, diamminenickel(II) tetracyanonickelate(II) di-biphenyl: Ni(NH<sub>3</sub>)<sub>2</sub>Ni(CN)<sub>4</sub>.2C<sub>12</sub>H<sub>10</sub>

T. Iwamoto, Tomoyuki Miyoshi, Yusuke Sasaki · Acta Crystallographica Section B · 1974 · 32 citations

, , +14