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Heterometal Clusters Ln<sub>2</sub>Na<sub>8</sub>(OCH<sub>2</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>12</sub>(OH)<sub>2</sub> as Homogeneous Catalysts for the Tishchenko Reaction
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Citations
20
References
2009
Year
Cluster ScienceInorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisReaction ScopeCluster ChemistryHomogeneous CatalystsCatalysisGroup 3ChemistryOrganometallic CatalysisMain Group ChemistryHomogeneous CatalysisCatalytic SynthesisTishchenko Reaction
Abstract The heterometal alkoxide clusters of Group 3 metal and lanthanides with sodium Ln 2 Na 8 (OCH 2 CH 2 NMe 2 ) 12 (OH) 2 (Ln=Y, lanthanide) were found to serve as highly active catalysts for the Tishchenko reaction of various aldehydes to form the corresponding esters. The reaction scope and the influence of lanthanide and sodium metal on the catalytic activity were investigated, and the proposed mechanism of the reaction was discussed.
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