Concepedia

Chiral (salen)Coiii catalyst for the synthesis of cyclic carbonatesElectronic supplementary information (ESI) available: general experimental procedures and analytical data for new compounds. See http://www.rsc.org/suppdata/cc/b4/b401543f/

Robert L. Paddock, SonBinh T. Nguyen

Chemical Communications · 2004 · 182 citations · 8 references

DOI

Concepts

Abstract

A catalyst system comprised of a CoIII(salen) complex and a Lewis base is investigated for the reaction of CO2 and a variety of epoxides to form cyclic carbonates. Application of this catalyst system in the kinetic resolution of propylene oxide is also discussed.

References

8

Catalysts for the reactions of epoxides and carbon dioxide

Donald J. Darensbourg · Coordination Chemistry Reviews · 1996 · 805 citations

, , +12

Chemical CO<sub>2</sub> Fixation:  Cr(III) Salen Complexes as Highly Efficient Catalysts for the Coupling of CO<sub>2</sub> and Epoxides

Robert L. Paddock, SonBinh T. Nguyen · Journal of the American Chemical Society · 2001 · 664 citations

, , +15

Cobalt‐Based Complexes for the Copolymerization of Propylene Oxide and CO<sub>2</sub>: Active and Selective Catalysts for Polycarbonate Synthesis

Zengquan Qin, C.M. Thomas, Stephen Lee et al. · Angewandte Chemie International Edition · 2003 · 411 citations · Full text

, , +15

Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, and Co Salen-Type Complexes

Yu‐Mei Shen, Wei‐Liang Duan, Min Shi · The Journal of Organic Chemistry · 2003 · 313 citations

, , +14

Catalytic Formation of Cyclic Carbonates from Epoxides and CO2 with Chromium Metalloporphyrinates

William J. Kruper, David D. Dellar · The Journal of Organic Chemistry · 1995 · 302 citations

, , +7